期刊
TETRAHEDRON LETTERS
卷 50, 期 34, 页码 4827-4829出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.05.119
关键词
Anomerization; Endocyclic cleavage; Pyranosides; Solvent effect
资金
- Japan Society for Promotion of Science [19590032, 21590036]
- RIKEN
- Grants-in-Aid for Scientific Research [19590032, 21590036] Funding Source: KAKEN
A pronounced solvent effect was observed in the anomerization reaction of pyranosides carrying 2,3-trans carbamate or carbonate. While significant anomerization from the beta- to alpha-direction was observed in CH3CN, none was observed in ether. (c) 2009 Elsevier Ltd. All rights reserved.
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