New fast synthesis route for symmetric and asymmetric phenyl-substituted photochromic dithienylethenes bearing functional groups such as alcohols, carboxylic acids, or amines

This Letter describes an efficient three-step synthesis route of symmetric and asymmetric phenyl-substituted photochromic 1,2-dithienylethenes bearing unprotected functional groups (i.e., alcohols, carboxylic acids or amines). These products can be easily obtained by typical Suzuki cross-coupling between photochromic dichlorides and commercial available boronic acids or pinacol esters. (C) 2009 Elsevier Ltd. All rights reserved.