4.4 Article

A simple and efficient hydrogenation of benzyl alcohols to methylene compounds using triethylsilane and a palladium catalyst

期刊

TETRAHEDRON LETTERS
卷 50, 期 43, 页码 5930-5932

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.08.043

关键词

Hydrogenolysis; Benzyl alcohols; Palladium(II) chloride; Triethylsilane; Reduction; Methylene compounds

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Hydrogenolysis of benzyl alcohols using triethylsilane (Et(3)SiH) and a catalytic amount of palladium(II) chloride (PdCl(2)) is described. The reaction takes place under mild conditions affording high yields of the corresponding methylene compounds in short reaction times. (C) 2009 Elsevier Ltd. All rights reserved.

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