期刊
TETRAHEDRON LETTERS
卷 50, 期 44, 页码 5984-5986出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.07.047
关键词
Macrodiolide; Pyrenophorol; Hydrolytic kinetic resolution (HKR); MacMillan alpha-hydroxylation; Horner-Wadsworth-Emmons reaction; Mitsunobu cyclization
资金
- UGC, New Delhi
An efficient stereoselective total synthesis of (-)-pyrenophorol 1 is described. The key steps involved in this synthesis are hydrolytic kinetic resolution (HKR), MacMillan alpha-hydroxylation, Horner-Wadsworth-Emmons (HWE) reaction, and Mitsunobu cyclization. (C) 2009 Elsevier Ltd. All rights reserved.
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