期刊
TETRAHEDRON LETTERS
卷 50, 期 48, 页码 6701-6704出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.09.089
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资金
- Consolidated Research Institute for Advanced Science and Medical Care
- Global COE program
- Ministry of Education, Culture, Sports, Science and Technology
The first total synthesis and structural determination of benzopyrenomycin has been achieved. This synthesis contains remarkable transformations including cyclization to afford the benzanthrone skeleton, syn-selective vinylogous Mukaiyama aldol reaction, and radical cyclization with the benzanthrone attaching the iodoalkane chain. (C) 2009 Elsevier Ltd. All rights reserved.
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