期刊
TETRAHEDRON LETTERS
卷 50, 期 26, 页码 3338-3340出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.02.091
关键词
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资金
- Korea Research Foundation [KRF-2008-313-C00483]
- Ministry of Education, Science and Technology [R32-2008-000-102170]
- CBMH
- Ministry of Education and Human Resources Development
- National Research Foundation of Korea [2008-313-C00483] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Efficient intermolecular hydroacylation of 1-alkene with aliphatic aldehyde was achieved using a catalyst mixture of cyclohexylamine, p-trifluoromethylbenzoic acid, Wilkinson's complex and 2-amino-3-picoline. The formation of unwanted aldol side-product was avoided through the conjugate addition of cyclohexylamine to the aldol intermediate that was initially generated, followed by the retro-Mannich-type fragmentation of the resulting beta-aminoaldimine.
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