期刊
TETRAHEDRON LETTERS
卷 49, 期 51, 页码 7322-7324出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.10.052
关键词
Cellulose; Aldopyranose; Ionic liquids; Imidazolium; BMIM; Reducing end; Isotopic labeling; Fluorescence labeling; Size exclusion chromatography
资金
- Austrian FWF [P-17426]
Ionic liquids with 1-alkyl-3-methyl-imidazolium cations react at C-2 with cellulose at its reducing end, forming a carbon-carbon bond. The reaction is strongly catalyzed by bases, such as the commonly present impurities in ILs, imidazole. and 1-methylimidazole. The direct reaction was verified by means of C-13-isotopical labeling and with the help of an IL that carried a fluorescence label which was transferred to cellulose upon the reaction. In solutions of cellulose in alkylmethylimidazolium ILs, both the ionic liquid and the cellulose are evidently not inert. (C) 2008 Elsevier Ltd. All rights reserved.
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