期刊
TETRAHEDRON LETTERS
卷 49, 期 20, 页码 3308-3311出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.03.057
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Thermal reaction of meso-meso, beta-beta, beta'-beta' triply linked diporphyrins with an azomethine ylide produced seven-membered cyclo-adducts via formal [3+4] cycloaddition at the bay-area. Bischlorin structures of the cycloadducts are characterized on the basis of spectroscopic data and confirmed by single crystal X-ray diffraction analysis. Interestingly, the stability of the cycloadducts depends on the central metal ions in the porphyrin core. (c) 2008 Elsevier Ltd. All rights reserved.
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