期刊
TETRAHEDRON LETTERS
卷 49, 期 33, 页码 4865-4868出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.06.014
关键词
oxidative kinetic resolution; secondary alcohol; Mn(III) salen; mesoporous silica SBA-15; supported ionic liquid
A supported ionic liquid strategy has been applied for the immobilization of a chiral Mn(III) salen complex onto ionic liquid modified mesoporous silica SBA-15. The immobilized catalyst demonstrated high enantioselectivity and activity in the oxidative kinetic resolution of secondary alcohols, and could be recycled five times without obvious loss of activity. (C) 2008 Elsevier Ltd. All rights reserved.
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