期刊
TETRAHEDRON LETTERS
卷 49, 期 46, 页码 6514-6517出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.08.108
关键词
Total synthesis; Botcinin; Botcinic acid; Botcinolide; Structural revision
资金
- Center for Green Photo-Science and Technology
- Ministry of Education, Science, Sports and Culture, Japan
The stereoselective total syntheses of botcinic acid, botcinic acid methyl ester, 3-O-acetylbotcinic acid methyl ester, botcineric acid, and botcinin E were achieved. The structures of these compounds have been unequivocally determined through their total synthesis, and they are identified with the revised structures of botcinolide, 4-O-methylbotcinolide, 3-O-acetyl-5-O-methylbotcinolide, homobotcinolide, and 2-epilbotcinolide, respectively. (C) 2008 Elsevier Ltd. All rights reserved.
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