期刊
TETRAHEDRON LETTERS
卷 49, 期 38, 页码 5544-5547出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.07.065
关键词
anion sensing; fluorescence probe; cyanide sensing; o-(carboxamido)trifluoroacetophenone
资金
- Korea Research Foundation [KRF-2005-070-C00078]
- Korea Health industry Development Institute [A05-0426-B20616-05N1-00010A]
- National Research Foundation of Korea [2005-070-C00078] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A novel fluorescence probe has been synthesized, which consists of o-(carboxamido)trifluoroacetophenone moiety as the recognition element and cyano-1,2-diphenylethylene moiety as the signaling unit. Fluorescence titrations of the probe with anions such as F-, Cl-, I-, CN-, SCN-, AcO-, H2PO4-, HSO4-, and ClO4- as their BU4N+ salts in acetonitrile show that CN- is the most efficient quencher, AcO- and F- follow it, and other anions show little changes. In an aqueous medium, MeOH-water (9:1), the probe shows fluorescence quenching only toward cyanide and no changes toward the other anions. (C) 2008 Elsevier Ltd. All rights reserved.
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