期刊
TETRAHEDRON LETTERS
卷 49, 期 13, 页码 2106-2110出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.01.122
关键词
fluorine-containing compounds; asymmetric tertiary carbon; enantioselective synthesis; rhodium; conjugate addition
Treatment of fluoroalkylated electron-deficient olefins with various boronic acids in the presence of a catalytic amount of Rh(l) coordinated with (S)-BINAP in toluene/H2O at the reflux temperature for 3 h gave the corresponding conjugate addition products with high enantioselectivity in high yields. (C) 2008 Elsevier Ltd. All rights reserved.
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