期刊
TETRAHEDRON LETTERS
卷 49, 期 16, 页码 2588-2591出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.02.089
关键词
oxidative cleavage; alkenes; tert-butyl hydroperoxide; indium(III) chloride; water
An efficient and general method for the oxidative cleavage of alkenes and alkynes using tert-butyl hydroperoxide and indium(III) chloride as catalyst in water to give the corresponding carboxylic acids or ketones has been achieved. The reaction conditions are compatible with sensitive moieties such as peptide bonds, tert-butyl carboxylic esters and N-Boc-protected tryptophan. The catalyst could be recycled. (c) 2008 Elsevier Ltd. All rights reserved.
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