4.4 Article

Novel cleavage of (E)-allyl vic-diols to aldehydes using the 2nd-generation Grubbs catalyst

期刊

TETRAHEDRON LETTERS
卷 49, 期 49, 页码 6988-6990

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.09.118

关键词

(E)-allyl vic-diol; Cleavage; 2nd-Generation Grubbs catalyst; Alkyl vic-diol

资金

  1. JSPS [16GS0206]
  2. Ministry of Education, Science, Sports and Culture, Japan
  3. Grants-in-Aid for Scientific Research [16GS0206] Funding Source: KAKEN

向作者/读者索取更多资源

Secondary (E)-allyl vic-diol cleavage in the presence of the 2nd-generation Grubbs catalyst has been developed. The position of a vic-diol adjacent to C=C plays a crucial role in the cleavage reaction compared to an alkyl vic-diol based on a model compound. (C) 2008 Elsevier Ltd. All rights reserved.

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