期刊
TETRAHEDRON LETTERS
卷 49, 期 36, 页码 5247-5251出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.06.112
关键词
chiral nitroxyl radical; enantioselective oxidation; optically active alcohol; electrooxidation
资金
- Ministry of Education, Science, Sports and Culture, Japan [19790017]
- Japan Society for the Promotion of Science [19550109]
- Konica Minolta Imaging Science Foundation, Japan.
Enantiomerically pure azabicyclo-N-oxyls were prepared from L-hydroxyproline. They mediated enantioselective electrooxidation of racemic sec-alcohols to afford optically active sec-alcohols with moderate to high s value (up to 21) (C) 2008 Elsevier Ltd. All rights reserved.
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