期刊
TETRAHEDRON
卷 74, 期 39, 页码 5683-5690出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2018.07.052
关键词
N-heterocyclic carbene-palladacyclic complex; Aryl chlorides; C-N coupling; alpha-arylation; Synthetic methods
资金
- National Natural Science Foundation of China [21471115]
N-Heterocyclic carbene-palladacyclic complexes 3 were successfully achieved in a one-pot procedure under mild conditions. The structure of 3a was unambiguously confirmed by X-ray single crystal diffraction and it was an active catalyst in the Buchwald-Hartwig amination and alpha-arylation of ketones even at very low catalyst loadings (0.01 mol%). (C) 2018 Elsevier Ltd. All rights reserved.
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