期刊
TETRAHEDRON
卷 70, 期 51, 页码 9652-9660出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2014.10.075
关键词
Copper; Chemoselective; 2-Mercaptobenzothiazole; PEG-400
资金
- Educational Commission of Jiangxi Province, China [GJJ13246]
- Science and Technology Planning Project of Jiangxi Province, China [20121BBG70015, 20122BAB213012]
A novel approach for chemoselective S- and N-arylation of 2-mercaptobenzothiazole was developed by copper/PEG-400 catalyst systems. Copper source and reaction temperature play an important role in this protocol, selective S-arylation of 2-mercaptobenzothiazole was achieved by using CuI/PEG-400/50 degrees C catalyst system, while selective N-arylation was achieved with CuO/PEG-400/140 degrees C catalyst system. Both are compatible with a variety of aryl halides and selectively give the desired S- and N-arylation products in good to excellent yields, respectively. (C) 2014 Elsevier Ltd. All rights reserved.
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