期刊
TETRAHEDRON
卷 70, 期 12, 页码 2195-2202出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2014.01.033
关键词
C-H activation; N-Methyl amines; Transition-metal-free; Potassium peroxodisulfate; Oxidation
资金
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- National Natural Science Foundation of China [21272257]
- Doctor Agglomeration Program of Jiangsu Province
A transition-metal-free oxidative methylenation reaction was developed. Methylene-bridged bis-1,3-dicarbonyl compounds were synthesized by oxidative C(Sp(3))-H activation and C-N cleavage of N-methyl amines. This novel reaction avoids the use of transition metal catalyst. Furthermore, the reaction are very mild and operational convenient. (C) 2014 Elsevier Ltd. All rights reserved.
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