期刊
TETRAHEDRON
卷 70, 期 45, 页码 8737-8743出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2014.09.023
关键词
Thiadiazoles; Nitrogen-sulfur bond formation; Imidoyl thioureas; Copper; Oxidative cyclization
资金
- Ministry of Trade, Industry Energy (MOTIE)
- Korea Institute for Advancement of Technology (KIAT) [R0002016, M0000338]
A copper-catalyzed N-S bond formation was utilized to produce 3-substituted-5-amino-1,2,4-thiadiazoles from imidoyl thioureas obtained by reaction of amidine hydrochlorides with isothiocyanates. Moreover, the 1,2,4-thiadiazoles were generated through a one-pot protocol without the isolation of the intermediates. This new method is highly efficient and convenient because it employs the cheap and environmentally friendly copper salt and can be conducted under air. (C) 2014 Elsevier Ltd. All rights reserved.
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