期刊
TETRAHEDRON
卷 69, 期 44, 页码 9237-9244出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.08.059
关键词
Palladium; Nanoscale metal-organic frameworks; Catalysis; Suzuki-Miyaura cross-coupling
资金
- 973 programs [2013CB933203]
- National Nature Science Foundation of China [21071143, 21131006]
- Nature Science Foundation of Fujian Province
Pd nanoparticles have been successfully supported on nanoscale metal-organic frameworks (NMOFs) by using a simple and effective microwave-assisted impregnation process. The resulting composite, representing as a highly active NMOFs supported metal nanoparticles catalyst for the Suzuki cross-coupling reaction between aryl/heteroaryl halides and arylboronic acids, is well characterized, and its high activity and good recyclability are discussed in details. It reveals that, compared to the corresponding bulk MOFs and conventional active carbon materials, nanoscale MOFs as novel support materials for heterogeneous catalysts can exhibit superior performance in the catalytic reactions. (C) 2013 Elsevier Ltd. All rights reserved.
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