期刊
TETRAHEDRON
卷 69, 期 31, 页码 6519-6526出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.05.025
关键词
Carbonylation; Phenanthridinone; Palladium-catalyzed; Free-amine; C-H activation
资金
- National Basic Research Program of China [2011CB936003]
- NSFC [21072169, 21272205]
- National Key Technology Research and Development Program [2012BAK25B03]
A Pd(OAc)(2)-catalyzed C(sp(2))-H carbonylation protocol of arenes under carbon monoxide atmosphere has been developed. The scope of the carbonylation reaction is broad and tolerates a variety of useful functional groups. This reaction provides a novel and efficient method for the synthesis of biologically and pharmaceutically significant phenanthridinones. (C) 2013 Elsevier Ltd. All rights reserved.
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