期刊
TETRAHEDRON
卷 69, 期 3, 页码 1086-1091出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.11.065
关键词
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资金
- NSFC [21132005, 91027005]
- Fok Ying Tung Education Foundation [131014]
- Department of Chemistry at Renmin University of China (People's Republic of China)
- Renmin University of China from the central government [12XNLI02]
- Young One-thousand-talents Scheme
The self-assembly process of a supramolecular tris(crown ether) hexagon with [G-1]-[G-3] dendritic dibenzylammonium cations was described. The resulted novel dendrimer systems organized with multiple intermolecular weak interactions were characterized with one-dimensional multinuclear (H-1 and P-31) and two-dimensional (H-1-H-1 NOESY and ROESY) NMR spectroscopy as well as CSI-TOF-MS spectrometry. It was found that with the introduction of multiple non-covalent intermolecular interactions, supramolecular self-assembly with multiple simple building blocks can effectively form complex higher order dendrimer system. This study implies a simple strategy (i.e., supramolecular self-assembly) to obtain novel dendrimer systems, which have received extensively attention not only for their esthetic beauty but also for their potential utility in a variety of applications where their structures and interiors are of potential benefit. (C) 2012 Elsevier Ltd. All rights reserved.
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