期刊
TETRAHEDRON
卷 69, 期 46, 页码 9761-9765出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.09.010
关键词
Palladium; Diazonium salts; Cross-coupling reactions; Aqueous medium
资金
- MICINN of Spain [CTQ2011-23121]
- Generalitat de Catalunya [2009SGR637]
- University of Girona
Aryl-heteroaryl and heteroaryl-heteroaryl compounds are obtained through the Suzuki-Miyaura cross-coupling reactions between diazonium salts and potassium trifluoroborates using PdCl2(CH3CN)(2) as the catalyst in water and in the absence of any additive, ligand or base. In addition, the same mild catalytic system is effective for the Matsuda-Heck reaction between several monoolefins with aryldiazonium salts. (C) 2013 Elsevier Ltd. All rights reserved.
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