期刊
TETRAHEDRON
卷 69, 期 26, 页码 5525-5536出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.04.097
关键词
Indole alkaloids; Total synthesis; Enantiospecific synthesis; Claisen rearrangement
资金
- Department of Science and Technology (DST), New Delhi
- Council of Scientific and Industrial Research (CSIR), New Delhi
An enantiospecific total synthesis of indole alkaloids eburnamonine, aspidospermidine and quebrachamine is described from lactic acid. Synthesis of all three alkaloids is accomplished from a single chiral building block. Johnson-Claisen rearrangement of a chiral allyl alcohol is the main feature for the installation of the required quaternary centre. (C) 2013 Elsevier Ltd. All rights reserved.
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