期刊
TETRAHEDRON
卷 69, 期 38, 页码 8129-8131出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.07.056
关键词
Visible light; Photocatalysis; Formamide; C-C bond cleavage; Ruthenium
资金
- National Science Foundation of China [20872004, 20972008]
- State Ministry of Science and Technology of China
- Shenzhen Bureau of Science, Technology and Information
- Shenzhen 'Shuang Bai Project'
A range of 1,2-vicinal diamines were smoothly converted into N,N-dialkylformamides under the synergistic actions of Ru(bpy)(3)Cl-2 photo-catalyst, 45 W household lighting bulb, and Cs2CO3 basic additive under very mild reaction conditions. The process involves visible light-enabled photo-catalytic cleavage of C-C bond as the strategic event. (C) 2013 Elsevier Ltd. All rights reserved.
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