期刊
TETRAHEDRON
卷 69, 期 27-28, 页码 5580-5587出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.04.114
关键词
-
资金
- NIH NIGMS [GM073836]
This paper describes the development of a mild Pd-catalyzed C-H arylation reaction using potassium aryltrifluoroborates in conjunction with Mn(OAc)3 as the oxidant. The scope of this transformation is explored with a variety of different aryltrifluoroborates and arylpyridine substrates. Preliminary mechanistic studies suggest that the reaction proceeds via a high-valent Pd mechanism with C-H activation occurring at or before the rate determining step. (C) 2013 Elsevier Ltd. All rights reserved.
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