期刊
TETRAHEDRON
卷 69, 期 50, 页码 10739-10746出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2013.10.064
关键词
Natural products; Stereoselective synthesis; Cross-coupling; Unconjugated alkylation; Chiral quaternary carbon
资金
- National Natural Foundation of China [21242008]
- Xi-Yuan Project of Fudan's Undergraduate Research Opportunities Program
A facile asymmetric synthesis of Delta(3)-2-Hydroxybakuchiol, Bakuchiol, and ent-Bakuchiol is described through one common intermediate bearing a chiral all-carbon quaternary carbon center, which involves stereoselectively unconjugated alkylation of the alpha,beta-unsaturated imide bearing Evans' auxiliary, Takai-Utimoto reaction, Negishi reaction, and Heck reaction as key steps. (C) 2013 Elsevier Ltd. All rights reserved.
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