期刊
TETRAHEDRON
卷 69, 期 22, 页码 4473-4478出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.11.060
关键词
Palladium; Arylation; C-H activation; Dehydrogenative cross-coupling
资金
- Ministere de l'Enseignement Superieur et de la Recherche
The synthesis of fused thiophene-cyclopentanes by Pd-II-catalyzed dehydrogenative C(sp(2))-H/C(sp(3))-H coupling is described. This reaction shows interesting chemo- and diastereoselectivity, however a direct comparison showed that it is yet much less efficient than the two-step sequence composed of electrophilic halogenation and Pd-0-catalyzed C(sp(3))-H arylation. (C) 2012 Elsevier Ltd. All rights reserved.
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