4.4 Article

Synthesis of α-ester-β-keto peroxides via iron-catalyzed carbonylation-peroxidation of α,β-unsaturated esters

期刊

TETRAHEDRON
卷 68, 期 50, 页码 10333-10337

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.09.110

关键词

Iron catalysis; Organic peroxides; Peroxidation; Carbonylation; Alkene di-functionalization

资金

  1. National Science Foundation of China [20832002, 21072223, 21272267]
  2. State Key Laboratory of Heavy Oil Processing [2012-1-06]
  3. Fundamental Research Funds for the Central Universities
  4. Renmin University of China [10XNL017]

向作者/读者索取更多资源

A general and practical method for the synthesis of alpha-ester-beta-keto peroxides has been achieved by iron-catalyzed three-component reactions of alkenes, aldehydes, and TBHP. A wide variety of functionalized organic peroxides were synthesized efficiently and selectively. (C) 2012 Elsevier Ltd. All rights reserved.

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