期刊
TETRAHEDRON
卷 68, 期 7, 页码 1869-1885出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.12.079
关键词
Heterocycles; IMDAF reactions; Polycyclic compounds; Stereoselectivity
资金
- The Norwegian Research Council [177368, 179568/V30]
- Bruker Avance instruments
Arenes and heteroarenes carrying a halogen and an amino- or hydroxy group have been converted to allylamino- or allyloxy-furyl-(hetero)arenes. These compounds underwent IMDAF reactions to give complex fused polycyclic heterocycles. The reactivity of the substrates was highly dependent on the detailed substitution pattern, however cyclizations occurred with high stereoselectivity in most cases. Experimental findings regarding reactivity and stereoselectivity were supported by calculations. (C) 2012 Elsevier Ltd. All rights reserved.
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