期刊
TETRAHEDRON
卷 68, 期 18, 页码 3611-3615出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2012.02.079
关键词
N-Heterocyclic carbenes; O-Alkylation; Benzoate derivatives; Aerobic oxidation
资金
- Natural Science Foundation of China [21002026]
- Fundamental Research Funds for the Central Universities
- Shanghai Committee of Science and Technology [11DZ2260600]
A NHCs-mediated benzoates formation was developed by treatment of aromatic aldehydes with alkyl halides in the presence of oxygen. Corresponding benzoate derivatives were obtained in high yields up to 99%. The reaction mechanism was also discussed and a NHCs-mediated O-alkylation and subsequent oxidation process was proposed. (C) 2012 Elsevier Ltd. All rights reserved.
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