期刊
TETRAHEDRON
卷 67, 期 26, 页码 4753-4757出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.04.107
关键词
Palladium-catalyzed; Reductive; Cyclization; Alkaloid; Salviadione
资金
- National Science Foundation [CHE-0611096]
- NSF-EPSCoR [1002165R]
An expedient synthesis of the alkaloid salviadione, the only to date isolated naturally occurring 1H-benzo [def]carbazole is described. The key step in the synthesis is a palladium-catalyzed, carbon monoxide-mediated reductive N-heterocyclization of a nitroarene with an adjacent alkene. (C) 2011 Elsevier Ltd. All rights reserved.
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