期刊
TETRAHEDRON
卷 67, 期 24, 页码 4333-4343出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.04.021
关键词
MIDA boronates; Iterative cross-coupling; Polyene natural products; cis-Alkenes
资金
- NIH [R01 GM080436]
Iterative cross-coupling represents a potentially general approach for the simple, efficient, and flexible construction of a wide range of functional small molecules. In this context, (Z)-(2-bromovinyl)-N-methyliminodiacetic acid (MIDA) boronate is a very useful building block for small molecule synthesis. This compound can serve as a starting material for the preparation of a wide range of cis-alkene-containing MIDA boronates. This compound can also be used for the iterative cross-coupling-based synthesis of various cis-olefin-containing targets. Collectively, these results contribute to the expanding generality of the MIDA boronate platform. (C) 2011 Elsevier Ltd. All rights reserved.
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