期刊
TETRAHEDRON
卷 67, 期 34, 页码 6369-6374出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.05.111
关键词
Heteroaryl ketone; 1,1-Dibromoethene; Tandem reaction; TBAF center dot 3H(2)O
资金
- National Natural Science Foundation of China [20972042, 20911140238]
- Innovation Scientists and Technicians Troop Construction Projects of Henan Province [104100510019]
A novel method for the synthesis of heteroaryl ketones through one-pot tandem reaction of 1,1-dibromoethenes with 2-amino(thio)phenols promoted by TBAF center dot 3H(2)O and RuCl3(5%)/air was developed. This novel method includes several reactions in one-pot and utilizes economical yet efficient reagents to generate synthetically and biologically interesting heteroaryl ketones under mild conditions with good efficiency. (C) 2011 Elsevier Ltd. All rights reserved.
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