期刊
TETRAHEDRON
卷 66, 期 31, 页码 5753-5761出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.04.125
关键词
Trifluoromethylation; Hypervalent iodine; X-ray analysis; Reactivity study; Monochloroiodane
资金
- ETH Zurich
- Swiss National Science Foundation
- SSCI (Stipendienfonds der Schweizerischen Chemischen Industrie)
- ETH
Several new five- and a six-membered heterocyclic monochloroiodanes, including two cationic species, were synthesized. Three of which were used for the preparation of corresponding trifluoromethylation reagents. These compounds were characterized by X-ray crystallography for a comparative structural study. A reactivity study on the trifluoromethylation of para-toluenesulfonic acid has been conducted in order to compare initial rates. Compounds having a longer I-O bond display a higher reactivity. (C) 2010 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据