期刊
TETRAHEDRON
卷 66, 期 46, 页码 8893-8898出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.09.060
关键词
Homogeneous catalysis; Enantioselective catalysis; Asymmetric hydrogen transfer reduction; beta-Aminoalcohols; Biomass
资金
- Ministere de la Recherche et de la Technologie
- CNRS
Starting from isosorbide and isomannide, two by-products from the starch industry, a family of chiral functionalized beta-aminoalcohols presenting a THF ring has been synthesized as potential ligands for hydrogen transfer reduction of prochiral ketones. Under optimal conditions, more than 70% ee with an excellent conversion were obtained for the HTR of the acetophenone. (C) 2010 Elsevier Ltd. All rights reserved.
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