期刊
TETRAHEDRON
卷 66, 期 35, 页码 7161-7168出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.06.080
关键词
(112,19Z)-3-Acetoxy-11,19-octacosadien-1-ol, (R)-, (S)-; and (+/-)-; Drosophila melanogaster; 3,4-Epoxy-1-butanol PMB ether, (R)- and (S)-; Jacobsen's hydrolytic kinetic resolution (HKR) of epoxide; Pheromone
资金
- Alexander von Humboldt Foundation
- Singapore National Research Foundation
- Singapore Millennium Foundation
The enantiomers of (11Z,19Z)-3-acetoxy-11,19-octacosadien-1-ol were synthesized from the enantiomers of 3,4-epoxy-1-butanol PMB ether. Its racemate was also synthesized. Its (S)-isomer and racemate were shown to possess the same pheromone activity as CH503, a long-lived inhibitor of male courtship in Drosophila melanogaster, although the racemate was less active. (C) 2010 Elsevier Ltd. All rights reserved.
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