期刊
TETRAHEDRON
卷 66, 期 34, 页码 6885-6888出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.06.054
关键词
Cycloalumination; Cyclomagnesiation cyclic alkynes; Zr complexes; Homogeneous catalysis; Macrocyclic ketones; Ozonolysis
资金
- Russian Foundation for Basic Research [10-03-00046]
- RF [MC-1039.2007.3, Sci.Sh.-2349.2008.3]
A new effective method for designing unique gigantic polyfunctional macrocarbocycles from cyclic acetylenes and Grignard reagents through the catalytic cyclometalation reaction in the presence of transition metal based complexes has been elaborated. (C) 2010 Elsevier Ltd. All rights reserved.
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