Donor-acceptor organic sensitizers assembled with isoxazole or its derivative 3-oxopropanenitrile

A series of new donor-acceptor organic sensitizers LJ5-LJ7 assembled with isoxazole or its derivative 3-oxopropanenitrile was synthesized and used in dye-sensitized solar cells to study the effect of both pi-spacers and anchoring groups on device performance. X-ray crystal structure analyses show planar arrangement of dithiophene and isoxazole fragments, providing an excellent pi conjugation and hence the large electronic coupling between the triphenylamine donor and electron acceptor units. For the DSSC applications, the derived photophysical and photovoltaic properties revealed a lower eta value of 1.06% (LJ7) and 2.41% (US), and 3.30% (LJ7) for the dyes with rhodanine-3-acetic acid, cyanoacetyl group, and vinyl cyanoacetic acid as the anchor. Electrochemical impedance spectroscopy was used to determine the interfacial charge transfer process occurring in solar cells that employed different dyes. Crown Copyright (C) 2010 Published by Elsevier Ltd. All rights reserved.