期刊
TETRAHEDRON
卷 66, 期 26, 页码 4811-4815出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.03.111
关键词
Amide; Palladium; Arylation; sp(3) C-H activation
资金
- Scripps Research Institute
- National Institutes of Health (NIGMS) [1 R01 GM084019-02]
- Amgen
- Eli Lilly
- A.P. Sloan Foundation
- Bristol Myers Squibb
Protocols to effect beta-arylation of sp(3) C-H bonds via Pd(II)/(IV) and Pd(0)/(II) catalytic cycles have been achieved using a newly developed monodentate CONHC6F5 directing group. These reactions provide an unprecedented means to functionalize sp(3) C-H bonds in aliphatic carboxylic acid-derived substrates. (C) 2010 Elsevier Ltd. All rights reserved.
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