期刊
TETRAHEDRON
卷 66, 期 2, 页码 498-503出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.11.046
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A novel and efficient approach for the synthesis of phosphine-containing alpha-amino acids bearing quaternary carbon is described. The key step involves the original nucleophilic addition of lithiated phosphines onto acyclic ene-carbamates concomitant with a spontaneous internal (N -> C) alkyloxycarbonyl migration. (C) 2009 Elsevier Ltd. All rights reserved.
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