期刊
TETRAHEDRON
卷 66, 期 27-28, 页码 5053-5058出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.04.134
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资金
- Japan Society for the Promotion of Science (JSPS)
- Uehara Memorial Foundation
- Program for Promotion of Basic and Applied Research for Innovations in the Bio-oriented Industry (BRAIN)
The enantioselective formal total synthesis of aplysin has been achieved utilizing a palladium-catalyzed addition of arylboronic acid to the allenic alcohol followed by the Eschenmoser/Claisen rearrangement as the key steps. (C) 2010 Elsevier Ltd. All rights reserved.
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