期刊
TETRAHEDRON
卷 66, 期 26, 页码 4894-4899出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.03.010
关键词
Organocatalyst; Asymmetric reaction; One-pot reaction; ene-Reaction
资金
- Ministry of Education, Culture, Sports, Science, and Technology (MEXT)
Chiral bicyclo[3.3.0]octatrienes with excellent enantioselectivity were synthesized from the simple starting materials of alpha,beta-unsaturated aldehyde and cyclopentadiene via one-pot operation, which consisted of a diphenylprolinol silyl ether-mediated ene-type reaction, intramolecular addition reaction of cyclopentadiene moiety with aldehyde and dehydration reaction. (C) 2010 Elsevier Ltd. All rights reserved.
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