期刊
TETRAHEDRON
卷 65, 期 27, 页码 5222-5227出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.04.075
关键词
Methylenecyclopropanes; Vinylidenecyclopropanes; N-Fluorodibenzenesulfonimide; Fluorinated derivatives
资金
- Shanghai Municipal Committee of Science and Technology [06XD14005, 08dj1400100-2]
- National Basic Research Program of China (973) [2009CB825300]
- National Natural Science Foundation of China [20872162, 20672127, 20732008, 20821002, 20702013]
Methylenecyclopropanes and vinylidenecyclopropanes undergo ring-opening reactions with N-fluoroclibenzenesulfonimide (NFSI) upon heating at 60 degrees C in tetrahydrofuran to give the corresponding fluorinated derivatives 2 and 6 in good to excellent yields. A plausible reaction mechanism has been discussed on the basis of previous literature. (C) 2009 Elsevier Ltd. All rights reserved.
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