期刊
TETRAHEDRON
卷 65, 期 33, 页码 6739-6745出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.06.063
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资金
- NIGMS NIH HHS [R01 GM065483, R01 GM065483-08] Funding Source: Medline
A rapid synthesis of the bicyclo[2.2.2]octane core of andibenin B via a nature-inspired intramolecular [4+2] cycloaddition is described. This cycloaddition permits the construction of a sterically congested bicycle and simultaneously establishes three new all-carbon quaternary stereogenic centers in a highly efficient fashion. (C) 2009 Elsevier Ltd. All rights reserved.
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