期刊
TETRAHEDRON
卷 65, 期 8, 页码 1567-1573出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.12.070
关键词
Diazocarbonyl compounds; Diazoimides; 3-Heteroarylpiperidin-2-ones; Indoles; Pyrroles; Rhodium(II) acetate
资金
- Ministry of Environment and Forests, New Delhi
- CSIR, New Delhi
Rhodium(II) catalyzed carbenoid reactions of 3-diazopiperidin-2-ones were carried out with indoles and pyrroles to afford the respective (3-indol-3-yl)- and (3-pyrrol-2-yl)piperidones with regioselectivity. Interestingly, the reaction of bis-diazoimide in the presence of Rh-2(OAc)(4) catalyst furnished diazacyclopenta[a]phenalenone in a tandem manner. (C) 2008 Elsevier Ltd. All rights reserved.
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