期刊
TETRAHEDRON
卷 65, 期 51, 页码 10637-10643出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.10.057
关键词
Hydrogen transfer; Reduction; Olefins; Nickel nanoparticles
资金
- Spanish Ministerio de Educacion y Ciencia (MEC) [CTQ2007-65218]
- Consolider Ingenio [2010-CSD2007-00006]
- Generalitat Valenciana [PROMETE02009/039]
Nickel nanoparticles have been found to effectively catalyse the hydrogen-transfer reduction of a variety of non-functionalised and functionalised olefins using 2-propanol as the hydrogen donor. The heterogeneous process has been shown to be highly chemoselective for certain substrates, with all the corresponding alkanes being obtained in high yields. A synthesis of the natural dihydrostilbene brittonin A is also reported based on the use of nickel nanoparticles. (C) 2009 Elsevier Ltd. All rights reserved.
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