期刊
TETRAHEDRON
卷 65, 期 22, 页码 4293-4297出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.03.063
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资金
- Department of Energy [DE-FG02-05ER46238]
- North Carolina Biotechnology Center
- NCSU Department of Chemistry
Here it is shown that 3-phenyl-2-amino isoquinoline acts as a simple mercury sensor. It is simple to synthesize. The molecule requires base/buffer to bind in a 1:1 stoichiometry with mercury ion. however. Otherwise, it acts as a sacrificial base, presumably to pick up a proton liberated during binding. This binding is characterized quantitatively. (C) 2009 Elsevier Ltd. All rights reserved.
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