期刊
TETRAHEDRON
卷 64, 期 50, 页码 11433-11439出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.08.072
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Free base porphyrin sheet 5 was prepared by demetalation of zinc complex 1, which was flow more conveniently prepared in 30% yield by oxidation of a mixture of tetraporphyrins, 8, 9, and 11. The H-1 NMR spectrum of 5 shows no indication of an aromatic ring current for the porphyrin rings and evidences the freezing of the pyrrolic NH protons at the most inner and cuter corner positions, both of which contrast sharply with strong aromatic ring currents and rapid NH tautomerism of normal porphyrins. DFT calculations supported the experimental results, suggesting that the enforced planar COT core Causes these unique properties. The free base 5 was transformed into Cu(II) complex 6 that exhibits antiferromagnetic interaction among the Cu(II) ions with J=-1.16 cm(-1). (C) 2008 Elsevier Ltd. All rights reserved.
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