期刊
TETRAHEDRON
卷 64, 期 51, 页码 11724-11731出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2008.10.009
关键词
Binuclear copper(II) complex; Bifunctional catalyst; Homogeneous process; Nitroaldol reaction; Aldehydes; Nitroalkanes
资金
- Department of Science and Technology, New Delhi
- Council of Scientific and Industrial Research, New Delhi
Chiral binuclear copper(II) Schiff base complexes 4a-g have been prepared from aldehydes 1a,b, (S)-amino alcohols 2a-f, and Cu(OAc)(2)center dot 1H(2)O in high yield. Their catalysis is studied for the addition of nitroalkanes to aldehydes at ambient conditions with 76:24 er. (C) 2008 Elsevier Ltd. All rights reserved.
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